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3Li6.94
Alkali Metalssolid at STPS-block

Lithium

Group: 1Period: 2Standard Atomic Weight: 6.94 u

Why is Lithium in this position?

Understanding the scientific rationale behind Lithium's position in the periodic table:

Group Assignment
Group 1

Belongs to Group 1 (Alkali metals) because its neutral atom has a single valence electron (2s¹).

Period Assignment
Period 2

Belongs to Period 2 because its outermost electron occupies the second principal shell (n=2).

Orbital Block
S-block

Belongs to the s-block because the differentiating electron enters the 2s subshell.

Chemical Category
Alkali Metals

Classified as an alkali metal due to its soft metallic texture, low melting point, and electropositive cation formation (Li⁺).

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 1]

Bohr Atomic Shell Model(2, 1)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

3 Protons (p⁺)4 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 1LiZ = 3

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):1 / 8 electrons (13%)
Aufbau Electron Configuration
1s² 2s¹

Neutral ground state configuration. Valence electrons: 1.

Atomic & Quantum Properties

Electronegativity (Pauling)0.98 Pauling
1st Ionization Energy520.2 kJ/mol
Electron Affinity-59.6 kJ/mol
Atomic Radius (empirical)167 pm
Common Oxidation States+1
Crystal StructureBCC

Physical & Thermal Properties

Density at STP0.534 g/cm³
Melting Point180.54 °C (453.69 K)
Boiling Point1342 °C (1615 K)
Magnetic OrderingParamagnetic
Discovery Year1817
Discovered ByJohan August Arfwedson

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Lithium-ion batteries for electric vehicles, smartphones, and laptops
  • Psychiatric mood-stabilizing medication (Lithium carbonate)
  • High-temperature lubricating greases for automotive and aerospace bearings
  • Specialty heat-resistant ceramics and glass cookware
Occurrence in Nature

Found in spodumene and petalite pegmatites, and extracted from subterranean salt-lake brines in South America and Australia.

Etymology & Name Origin

From Greek 'lithos' meaning stone, since it was discovered in mineral ore

Important Chemical Compounds
Li₂CO₃ (Lithium carbonate)
LiOH (Lithium hydroxide)
LiCoO₂ (Lithium cobalt oxide)
LiPF₆ (Lithium hexafluorophosphate)
Interesting Chemical Facts
  • Lithium is one of only three elements (along with H and He) produced during the primordial Big Bang nucleosynthesis.
  • It has the highest specific heat capacity of any solid element (3.58 J/g·K).
  • It reacts with water vigorously, releasing flammable hydrogen gas and forming a caustic alkaline solution.
Safety & Handling Note

Highly reactive and flammable metal; reacts corrosively with moisture on skin, eyes, and mucous membranes.