#50 / 118
50Sn118.71
Post-Transition Metalssolid at STPP-block

Tin

Group: 14Period: 5Standard Atomic Weight: 118.71 u

Why is Tin in this position?

Understanding the scientific rationale behind Tin's position in the periodic table:

Group Assignment
Group 14

Belongs to Group 14 because it has 4 valence electrons (5s² 5p²).

Period Assignment
Period 5

Belongs to Period 5 because its outermost electrons occupy n=5.

Orbital Block
P-block

Belongs to the p-block because its valence electrons occupy 5p orbitals.

Chemical Category
Post-Transition Metals

Classified as a post-transition metal due to lower ionization energy and distinct metallic character compared to silicon and germanium.

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 18, 18, 4]

Bohr Atomic Shell Model(2, 8, 18, 18, 4)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

50 Protons (p⁺)69 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 18Shell M: Electron 2 of 18Shell M: Electron 3 of 18Shell M: Electron 4 of 18Shell M: Electron 5 of 18Shell M: Electron 6 of 18Shell M: Electron 7 of 18Shell M: Electron 8 of 18Shell M: Electron 9 of 18Shell M: Electron 10 of 18Shell M: Electron 11 of 18Shell M: Electron 12 of 18Shell M: Electron 13 of 18Shell M: Electron 14 of 18Shell M: Electron 15 of 18Shell M: Electron 16 of 18Shell M: Electron 17 of 18Shell M: Electron 18 of 18NShell N: Electron 1 of 18Shell N: Electron 2 of 18Shell N: Electron 3 of 18Shell N: Electron 4 of 18Shell N: Electron 5 of 18Shell N: Electron 6 of 18Shell N: Electron 7 of 18Shell N: Electron 8 of 18Shell N: Electron 9 of 18Shell N: Electron 10 of 18Shell N: Electron 11 of 18Shell N: Electron 12 of 18Shell N: Electron 13 of 18Shell N: Electron 14 of 18Shell N: Electron 15 of 18Shell N: Electron 16 of 18Shell N: Electron 17 of 18Shell N: Electron 18 of 18OShell O: Electron 1 of 4Shell O: Electron 2 of 4Shell O: Electron 3 of 4Shell O: Electron 4 of 4SnZ = 50

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):18 / 18 electrons (100%)
Shell N (n=4):18 / 32 electrons (56%)
Shell O (n=5):4 / 50 electrons (8%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p²

Neutral ground state configuration. Valence electrons: 4.

Atomic & Quantum Properties

Electronegativity (Pauling)1.96 Pauling
1st Ionization Energy708.6 kJ/mol
Electron Affinity-116 kJ/mol
Atomic Radius (empirical)145 pm
Common Oxidation States+4, +2
Crystal StructureTetragonal / Diamond Cubic

Physical & Thermal Properties

Density at STP7.29 g/cm³ (white)
Melting Point231.93 °C (505.08 K)
Boiling Point2602 °C (2875 K)
Magnetic OrderingDiamagnetic
Discovery YearAncient
Discovered ByKnown since prehistoric antiquity (~3000 BC, Bronze Age)

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Lead-free electrical solder for assembling printed circuit boards and microchips
  • Tin-plated steel cans ('tin cans') for hermetic food preservation
  • Bronze alloy casting (copper-tin alloy for bells, sculptures, and ship propellers)
  • Float glass manufacturing (molten glass floating on a smooth bath of molten tin)
Occurrence in Nature

Mined primarily from cassiterite (tinstone / SnO₂) placer sand deposits in China, Indonesia, and Myanmar.

Etymology & Name Origin

From Germanic root 'tin'; symbol Sn from Latin 'stannum'

Important Chemical Compounds
SnO₂ (Tin dioxide)
SnCl₂ (Stannous chloride)
SnF₂ (Stannous fluoride in toothpaste)
ITO (Indium tin oxide)
Interesting Chemical Facts
  • When cooled below 13.2 °C, metallic white tin (beta-tin) slowly mutates into a brittle gray nonmetallic powder (alpha-tin), a phenomenon known as 'tin pest'.
  • Legend says Napoleon's army retreated disastrously from Russia in 1812 partly because freezing winter temperatures turned their tin uniform buttons into powder.
  • Tin has 10 stable isotopes—the highest number of stable isotopes of any element in the periodic table.
Safety & Handling Note

Elemental tin is non-toxic and food-safe, but organotin compounds (tributyltin / TBT) are toxic marine pollutants.