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31Ga69.723
Post-Transition Metalssolid at STPP-block

Gallium

Group: 13Period: 4Standard Atomic Weight: 69.723 u

Why is Gallium in this position?

Understanding the scientific rationale behind Gallium's position in the periodic table:

Group Assignment
Group 13

Belongs to Group 13 because it has 3 valence electrons (4s² 4p¹).

Period Assignment
Period 4

Belongs to Period 4 because its outermost electrons occupy principal quantum level n=4.

Orbital Block
P-block

Belongs to the p-block because its differentiating electron enters a 4p orbital.

Chemical Category
Post-Transition Metals

Classified as a post-transition metal due to higher electronegativity and lower melting point than preceding transition metals.

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 18, 3]

Bohr Atomic Shell Model(2, 8, 18, 3)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

31 Protons (p⁺)39 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 18Shell M: Electron 2 of 18Shell M: Electron 3 of 18Shell M: Electron 4 of 18Shell M: Electron 5 of 18Shell M: Electron 6 of 18Shell M: Electron 7 of 18Shell M: Electron 8 of 18Shell M: Electron 9 of 18Shell M: Electron 10 of 18Shell M: Electron 11 of 18Shell M: Electron 12 of 18Shell M: Electron 13 of 18Shell M: Electron 14 of 18Shell M: Electron 15 of 18Shell M: Electron 16 of 18Shell M: Electron 17 of 18Shell M: Electron 18 of 18NShell N: Electron 1 of 3Shell N: Electron 2 of 3Shell N: Electron 3 of 3GaZ = 31

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):18 / 18 electrons (100%)
Shell N (n=4):3 / 32 electrons (9%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p¹

Neutral ground state configuration. Valence electrons: 3.

Atomic & Quantum Properties

Electronegativity (Pauling)1.81 Pauling
1st Ionization Energy578.8 kJ/mol
Electron Affinity-28.9 kJ/mol
Atomic Radius (empirical)136 pm
Common Oxidation States+3
Crystal StructureOrthorhombic

Physical & Thermal Properties

Density at STP5.91 g/cm³ (solid)
Melting Point29.76 °C (302.91 K)
Boiling Point2400 °C (2673 K)
Magnetic OrderingDiamagnetic
Discovery Year1875
Discovered ByPaul-Émile Lecoq de Boisbaudran

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • Gallium nitride (GaN) high-efficiency fast-charging adapters and blue/violet LEDs
  • Gallium arsenide (GaAs) high-frequency microwave chips for 5G smartphones and radar
  • Non-toxic liquid metal thermometers and computer thermal interface paste (Galinstan)
  • High-efficiency multijunction solar cells powering space satellites
Occurrence in Nature

Does not occur free in nature; extracted in trace amounts as a byproduct of bauxite (aluminium) and zinc refining.

Etymology & Name Origin

From Latin 'Gallia' meaning France; also an allusion to discoverer Lecoq ('le coq' = the rooster / Latin 'gallus')

Important Chemical Compounds
GaAs (Gallium arsenide)
GaN (Gallium nitride)
Ga₂O₃ (Gallium oxide)
GaCl₃ (Gallium trichloride)
Interesting Chemical Facts
  • Gallium is one of Mendeleev's most triumphant predictions; he predicted its atomic weight, density, and low melting point in 1871 under the name 'eka-aluminium'.
  • Gallium expands by 3.1% when it solidifies, meaning it should never be stored in glass or rigid metal containers as it will shatter them.
  • A drop of liquid gallium rapidly diffuses into aluminium grain boundaries, making tough aluminium metal as brittle as wet cardboard.
Safety & Handling Note

Low biological toxicity, but liquid gallium wets and stains glass and human skin, and severely embrittles aluminium structures.