#57 / 118
57La138.91
Lanthanides (Rare Earths)solid at STPD-block

Lanthanum

Group: f-blockPeriod: 6Standard Atomic Weight: 138.91 u

Why is Lanthanum in this position?

Understanding the scientific rationale behind Lanthanum's position in the periodic table:

Group Assignment
Group Lanthanide / Actinide

Serves as the lead element of the Lanthanides (historically Group 3) filling the 4f/5d energy levels.

Period Assignment
Period 6

Belongs to Period 6 because its valence electrons fill the n=6 shell (6s²).

Orbital Block
D-block

Electronically a d-block element ([Xe] 5d¹ 6s²), but classified as the first member of the f-block lanthanide series.

Chemical Category
Lanthanides (Rare Earths)

Classified as a lanthanide rare earth metal with typical trivalent chemistry (+3).

Atomic Structure & Bohr Shell Model

Shell Distribution: [2, 8, 18, 18, 9, 2]

Bohr Atomic Shell Model(2, 8, 18, 18, 9, 2)

Hover or tap any shell orbit ring to inspect electron counts and 2n² capacities.

57 Protons (p⁺)82 Neutrons (n⁰)
KShell K: Electron 1 of 2Shell K: Electron 2 of 2LShell L: Electron 1 of 8Shell L: Electron 2 of 8Shell L: Electron 3 of 8Shell L: Electron 4 of 8Shell L: Electron 5 of 8Shell L: Electron 6 of 8Shell L: Electron 7 of 8Shell L: Electron 8 of 8MShell M: Electron 1 of 18Shell M: Electron 2 of 18Shell M: Electron 3 of 18Shell M: Electron 4 of 18Shell M: Electron 5 of 18Shell M: Electron 6 of 18Shell M: Electron 7 of 18Shell M: Electron 8 of 18Shell M: Electron 9 of 18Shell M: Electron 10 of 18Shell M: Electron 11 of 18Shell M: Electron 12 of 18Shell M: Electron 13 of 18Shell M: Electron 14 of 18Shell M: Electron 15 of 18Shell M: Electron 16 of 18Shell M: Electron 17 of 18Shell M: Electron 18 of 18NShell N: Electron 1 of 18Shell N: Electron 2 of 18Shell N: Electron 3 of 18Shell N: Electron 4 of 18Shell N: Electron 5 of 18Shell N: Electron 6 of 18Shell N: Electron 7 of 18Shell N: Electron 8 of 18Shell N: Electron 9 of 18Shell N: Electron 10 of 18Shell N: Electron 11 of 18Shell N: Electron 12 of 18Shell N: Electron 13 of 18Shell N: Electron 14 of 18Shell N: Electron 15 of 18Shell N: Electron 16 of 18Shell N: Electron 17 of 18Shell N: Electron 18 of 18OShell O: Electron 1 of 9Shell O: Electron 2 of 9Shell O: Electron 3 of 9Shell O: Electron 4 of 9Shell O: Electron 5 of 9Shell O: Electron 6 of 9Shell O: Electron 7 of 9Shell O: Electron 8 of 9Shell O: Electron 9 of 9PShell P: Electron 1 of 2Shell P: Electron 2 of 2LaZ = 57

Educational Note: This Niels Bohr planetary model visually illustrates principal quantum energy shells ($n=1, 2, 3\dots$) and electron counts. In modern quantum mechanics (Schrödinger model), electrons do not orbit in fixed circular planetary tracks, but exist as 3D probability clouds (orbitals: $s, p, d, f$) governed by the Heisenberg uncertainty principle.

Electron Shell Filling Breakdown

Shell K (n=1):2 / 2 electrons (100%)
Shell L (n=2):8 / 8 electrons (100%)
Shell M (n=3):18 / 18 electrons (100%)
Shell N (n=4):18 / 32 electrons (56%)
Shell O (n=5):9 / 50 electrons (18%)
Shell P (n=6):2 / 72 electrons (3%)
Aufbau Electron Configuration
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 5d¹ 6s²

Neutral ground state configuration. Valence electrons: 3.

Atomic & Quantum Properties

Electronegativity (Pauling)1.1 Pauling
1st Ionization Energy538.1 kJ/mol
Electron Affinity-53 kJ/mol
Atomic Radius (empirical)195 pm
Common Oxidation States+3
Crystal StructureDouble HCP

Physical & Thermal Properties

Density at STP6.16 g/cm³
Melting Point920 °C (1193 K)
Boiling Point3464 °C (3737 K)
Magnetic OrderingParamagnetic
Discovery Year1839
Discovered ByCarl Gustaf Mosander

Real-World Uses, Occurrence & Compounds

Major Industrial & Everyday Uses
  • High-index low-dispersion optical glass for premium camera and telescope lenses
  • Hybrid electric vehicle nickel-metal hydride (NiMH) battery anodes (LaNi₅)
  • Petroleum fluid catalytic cracking (FCC) catalysts refining crude oil into gasoline
  • Carbon arc studio lighting for motion picture filming
Occurrence in Nature

Found in rare earth phosphate ores monazite and bastnäsite alongside other light lanthanides.

Etymology & Name Origin

From Greek 'lanthanein' meaning to lie hidden

Important Chemical Compounds
La₂O₃ (Lanthanum oxide)
LaNi₅ (Hydrogen storage alloy)
LaB₆ (Lanthanum hexaboride electron cathode)
Interesting Chemical Facts
  • A Toyota Prius hybrid car battery pack contains approximately 10 to 15 kilograms of lanthanum.
  • Lanthanum hexaboride (LaB₆) crystals serve as long-life high-brightness thermionic cathodes in transmission electron microscopes (TEM).
  • Lanthanum gives its name to the entire Lanthanide series (Z=57 to 71).
Safety & Handling Note

Low to moderate toxicity; lanthanum powder is combustible and reacts slowly with cold water to generate hydrogen.